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Material Safety Data Sheet for Cocamidopropyl Betaine (CAB)

Identification

Product Name: Cocamidopropyl Betaine
Synonyms: CAPB, Amides, Coco, N-(carboxymethyl)-N,N-dimethyl-, inner salt
CAS Number: 61789-40-0
Recommended Use: Surfactant in cleaning and personal care products
Supplier Contact: Name, address, phone, emergency number
Manufacturer: Name, address, phone, emergency number
Email Contact: Provided by the supplier
Emergency Telephone: Available 24/7 in accordance with local regulations
Date of Issue: Month and year of latest revision

Hazard Identification

GHS Classification: Eye irritation, Skin irritation, Non-flammable liquid
Label Elements: Hazard pictograms (irritant/exclamation mark), Signal word: Warning
Hazard Statements: Causes eye irritation, Causes mild skin irritation
Precautionary Statements: Wash hands thoroughly after handling, Wear eye/face protection, Keep out of reach of children
Potential Health Effects: Skin contact may cause redness for sensitive individuals, Splashes may irritate eyes, Inhalation is unlikely unless aerosolized, Ingestion could bring mild gastrointestinal upset
Environmental Hazards: Not classified as hazardous but avoid large releases to waterways

Composition / Information on Ingredients

Cocamidopropyl Betaine: 30-40% by weight
Water: 60-70% by weight
Preservatives: Trace amounts, typically less than 1% e.g., sodium benzoate or similar
Fatty Acid Source: Natural coconut oil derivatives, less than 1% downstream reactants
Impurities: Residual amidoamines, small percentage not expected to contribute to hazard classification, typically below 1%

First Aid Measures

Eye Contact: Rinse immediately with plenty of water for 15 minutes, remove contact lenses, keep eyelids open, seek medical advice if irritation persists
Skin Contact: Wash with soap and water, remove contaminated clothing, seek medical attention if rash or irritation develops
Inhalation: Move to fresh air, support breathing as needed, get medical attention if symptoms like headaches or dizziness occur but inhalation is rare with typical product forms
Ingestion: Rinse mouth thoroughly, drink small quantities of water, do not induce vomiting, consult poison center or physician
Notes to Physician: Treat symptomatically, no specific antidote known

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry powder, carbon dioxide
Unsuitable Extinguishing Media: Direct water jets on undiluted product may spread chemical
Specific Hazards: Substance is non-flammable but may decompose at high temperature to produce nitrogen oxides, carbon monoxide, carbon dioxide
Special Protective Equipment: Firefighters use self-contained breathing apparatus and full protective gear
Additional Information: Contaminated runoff should not enter drains, dike fire water for later disposal in accordance with local laws

Accidental Release Measures

Personal Precautions: Wear gloves, safety goggles to prevent skin and eye exposure, use apron if large volume is handled
Environmental Precautions: Prevent product from entering sewers or surface waters, inform authorities if significant release occurs
Methods for Clean-up: Absorb with inert material like sand or earth, scoop up and place in suitable container labeled for chemical waste, wash affected area with copious amounts of water, ventilate area
Reference to Other Sections: See exposure control, disposal, and handling sections for more information.

Handling and Storage

Handling: Maintain proper industrial hygiene, avoid splashes and aerosols, wear appropriate PPE (gloves, goggles), do not eat, drink or smoke during use, wash hands after handling
Storage: Store in cool, dry, well-ventilated space, keep containers tightly closed and upright, avoid extreme temperatures, segregate from oxidizing agents
Incompatible Materials: Strong acids and bases, oxidizing chemicals, excessive heat
Storage Conditions: Recommended temperature: 5–30°C, protect from direct sunlight, avoid freezing, keep away from food and beverages

Exposure Controls and Personal Protection

Occupational Exposure Limits: Not established for cocamidopropyl betaine, observe standard hygiene controls
Engineering Controls: Local exhaust for bulk handling, dilute solutions in normal use do not need special ventilation
Personal Protection Equipment: Protective gloves (nitrile, latex), splash goggles, apron for substantial exposure, respiratory protection if misting
Hygiene Measures: Remove contaminated clothing, wash before reuse, practice regular handwashing
Environmental Exposure Control: Avoid discharge to waterways, use containment for bulk handling

Physical and Chemical Properties

Appearance: Clear to yellowish liquid
Odor: Characteristic, mild, slightly fatty odor
pH (neat solution): 5.0–7.0
Melting Point: Not applicable (liquid at room temp)
Boiling Point: Approximately 100°C (water-based solution)
Solubility: Soluble in water
Density: 1.05–1.10 g/cm³
Flash Point: Not flammable
Viscosity: Varies according to concentration
Partition Coefficient (log Kow): Not available for mixture
Vapor Pressure: Not significant under standard conditions

Stability and Reactivity

Chemical Stability: Stable under normal handling and storage conditions
Reactivity: No dangerous reactions under recommended conditions
Hazardous Reactions: Contact with strong acids or oxidizers may cause decomposition
Conditions to Avoid: Excessive heat, freezing, direct sunlight
Materials to Avoid: Strong oxidizing agents, strong bases, concentrated acids
Decomposition Products: Under fire conditions, forms carbon oxides, nitrogen oxides, possibly toxic fumes

Toxicological Information

Acute Toxicity (oral/dermal/inhalation): Low toxicity by all routes based on animal data and widespread product use
Skin Irritation: Mild irritant potential, more frequent in sensitive individuals or prolonged skin contact
Eye Irritation: Moderate irritant potential, especially with direct splashes
Respiratory: Low inhalation risk unless aerosolized
Sensitization: Occasional reports of skin sensitization, rare in the general population
Chronic Toxicity: No significant chronic effects reported with normal use concentrations
Carcinogenicity: Not classified, not listed by IARC, NTP or OSHA
Mutagenicity: No evidence in available studies
Reproductive Toxicity: Not reported in animal or human studies

Ecological Information

Aquatic Toxicity: Low to moderate toxicity toward aquatic organisms, most formulations easily biodegradable
Persistence and Degradability: Readily biodegradable, breaks down in wastewater treatment
Bioaccumulation Potential: Not expected to bioaccumulate in aquatic life
Mobility in Soil: Dissolves and moves with water, limited data suggest little risk to groundwater
Other Adverse Effects: Large quantities can alter pH in aquatic environments, keep out of storm drains and surface waters

Disposal Considerations

Product Disposal: Dispose according to local, regional and national regulations, dilute small quantities with plenty of water for drain disposal if permitted, large quantities require collection by licensed disposal contractor
Contaminated Packaging: Wash and recycle or dispose as controlled waste, do not reuse packaging for food or beverages
Special Precautions: Do not introduce undiluted material into sewage systems or natural bodies of water, keep detailed records of quantity and disposal route

Transport Information

UN Number: Not regulated
UN Proper Shipping Name: Not applicable
Transport Hazard Class: Not regulated as dangerous goods
Packing Group: Not regulated
Environmental Hazards: Not a marine pollutant
Special Precautions for User: Prevent container damage, secure loads to avoid leaks, ensure safety data sheets travel with shipment for bulk quantities

Regulatory Information

Workplace Regulations: Subject to general chemical safety controls, OSHA Hazard Communication Standard applies
Global Inventory Listings: Listed on TSCA (US), DSL (Canada), EINECS/ELINCS (EU), AICS (Australia), ENCS (Japan), and most major chemical inventories
Labeling Requirements: Must include hazard statements and precautionary measures as outlined by GHS and local laws
Restrictions: Some countries set limits or labeling requirements for amidoamine or nitrosamine impurities
Right-to-Know Laws: States such as California may require notification if ingredient contains certain impurities
Other Regulations: Complies with REACH pre-registration for EU, included in GRAS list for specific uses but final products must meet local legal requirements for intended application